Cavity frequency-dependent theory for vibrational polariton chemistry

Cavity frequency-dependent theory for vibrational polariton chemistry

Recent experiments show the management of chemical reactivities by coupling molecules inside an optical microcavity. In distinction, transition state theory predicts no change of the response barrier top throughout this┬ácourse of. Here, we current a theoretical rationalization of the cavity modification of the bottom state reactivity within the vibrational robust…